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SDS for Asphalt

SDSforAsphalt  (click to get downloaded PDF copy)     Revised: 16 January 2016

SAFETY DATA SHEET for GOH manufactured asphalt

OSHA HCS (29 CFR 1910.1200)

Product identifier Hot / Warm Mix Asphalt
Chemical Name Mixture
CAS No. Mixture
Trade Name(s) Petroleum Asphalt / Road Paving Asphalt / Hot Mix Asphalt / Blacktop / Bitumen / Warm Mix Asphalt
Relevant identified uses of the substance or mixture and uses advised against
Identified Use(s) Road Paving Asphalt
Uses Advised Against None.
Details of the supplier of the safety data sheet
Company Identification Glenn O. Hawbaker Inc. 711 East College Ave. Bellefonte, PA 16823
Telephone (814) 221-1355
Emergency telephone number
Emergency Phone No. Not classified as dangerous for supply/use. Please contact the supplier above during normal business hours.

 

 

Classification of the substance or mixture
OSHA HCS (29 CFR 1910.1200) / GHS Classification Not classified as dangerous for supply/use.
Label elements
Hazard Symbol None
Signal Word(s) None
Hazard Statement(s) None
Precautionary Statement(s) None
Other hazards  

Contact with hot ASPHALT PAVING MATERIALS causes skin burns. May cause eye irritation.

Fumes may cause upper respiratory irritation (nose & throat). Skin contact may increase susceptibility to sunburn.

Poisonous hydrogen sulfide gas can accumulate in the head-space of containers of certain asphalt products.

Mechanical disruption (e.g., milling, cutting, chipping) of cured asphalt pavement may release crystalline silica dust from the aggregate.

 

Additional Information

 

Avoid breathing dust/fume/gas/mist/vapors/spray.

As necessary, Wear protective gloves/protective clothing/eye protection/face protection.

Wash hands and exposed skin after use.

 

 

 

Composition/information on ingredients % wt. CAS No.
Aggregate (crushed stone, sand, gravel, slag) 70 – 97 Various
Petroleum asphalt / bitumen^ 3 – 7 8052-42-4
Reclaimed Asphalt Pavement (RAP) 0 – 35 Mixture
Reclaimed Asphalt Shingles (RAS) 0 – 10 Mixture
Polymers and Natural Rubbers < 0.5 Various
Process oils (inherent in refined petroleum asphalt) < 0.1 Various
Anti-strip or other amine-based additives < 0.1 Various
Warm-mix additives < 0.1 Various

^Contains: <0.05% of 3 – 7 ring Polycyclic Aromatic Hydrocarbons (PAHs).

Other Substances in the product which may present a health or environmental hazard, or which have been assigned occupational exposure limits, are detailed below. Please see Section 8 of SDS for more details.

  • Contains: <0.1% airborne crystalline silica (inherent in aggregate) and <0.1% hydrogen
  • Hydrogen sulfide gas can accumulate in the head space of containers of certain asphalt
  • Heated product releases asphalt

 

Additional Information – None

 

 

Description of first aid measures
Inhalation Not normally required. Move person to fresh air. Apply artificial respiration if necessary. If symptoms persist, obtain medical attention.
Skin Contact Causes burns. Immediately cool skin where asphalt binder has adhered to skin. Allow asphalt binder which remains on the skin to fall off naturally. DO NOT REMOVE. If problem persist or coverage is extensive, get medical attention.
Eye Contact Flush eyes with water for at least 15 minutes while holding eyelids open. Remove contact lenses, if present and easy to do. Continue rinsing. If irritation develops and persists, get medical attention.
Ingestion Not normally required. Do not induce vomiting. Do not give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell.
 

Most important symptoms and effects, both acute and delayed

 

None known

Indication of any immediate medical attention and special treatment needed None known

 

 

 

Extinguishing Media
-Suitable Extinguishing Media Extinguish with carbon dioxide, dry chemical, foam or water spray.
-Unsuitable Extinguishing Media None anticipated.
Special hazards arising from the substance or mixture Combustion causes toxic fumes. Combustion products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides
Advice for fire-fighters A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions.

 

 

 

Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes.
Environmental precautions Not normally required.
Methods and material for containment and cleaning up Allow product to cool/solidify and pick up as a solid.
Reference to other sections None
Additional Information None.

 

 

Precautions for safe handling Avoid contact with skin and eyes.
Conditions for safe storage, including any incompatibilities
-Storage temperature Store at temperatures not exceeding the product’s flash point.
-Incompatible materials Strong oxidizing agents.

 

Control parameters Occupational Exposure Limits

 

 

 

SUBSTANCE.

 

 

CAS No.

(8hr TWA) (STEL)  

 

Note:

PEL (OSHA) * TLV (ACGIH) PEL (OSHA) TLV (ACGIH)
Asphalt fume —— —— 0.5 mg/m3 (I) —— —— See below
Crystalline Silica (respirable particulate)  

——

10 mg/m3

%SiO2  + 2

 

0.025 mg/m3 ^

 

——

 

——

 

See below

 

Hydrogen sulfide

 

7783-06-4

 

——

 

1 ppm

 

20 ppm ceiling

 

5 ppm

 

50 ppm peak

(I) Inhalable benzene-soluble fraction; ^Suspected Human Carcinogen; *Refer to OSHA 29 CFR 1910.1000 & 29 CFR 1926.55; 8hr TWA = 8 hour time-weighted average; STEL = Short Term Exposure Limit.

Recommended monitoring method                                      NIOSH 5042 (Asphalt Fume), NIOSH 7500 (Crystalline Silica), Electrochemical sensor (hydrogen sulfide).

Exposure controls

Appropriate engineering controls                                         Use only outdoors or in a well-ventilated area.

Personal protection equipment

 

Eye/face protection                                                               The following to be used as necessary: Safety Glasses

 

 

 

Skin protection (Hand protection/ Other)

 

The following to be used as necessary: Leather or thick textile gloves.
Respiratory protection

 

In case of inadequate ventilation wear respiratory protection. Use NIOSH approved respiratory protection. Air-purifying respirator with combination organic vapor cartridge / particulate filter may be sufficient. Check with protective equipment manufacturer’s data.
Thermal hazards Use gloves with insulation for thermal protection, when needed.
Environmental Exposure Controls Do not discharge waste and/or cleaning water via public sewer system. Ensure waste is collected and contained.

 

 

Information on basic physical and chemical properties
Appearance Solid
Color. Dark brown / Black
Odor Asphalt / Bitumen
Odor Threshold (ppm) Not available.
pH (Value) Not available.
Melting Point (°C) / Freezing Point (°C) Not available.
Boiling point/boiling range (°C): > 371 (>700 ºF)
Flash Point (°C) > 232 (> 450 ºF)
Evaporation Rate Not available.
Flammability (solid, gas) Not applicable.
Explosive Limit Ranges Not applicable.
Vapor pressure (Pascal) Not determined.
Vapor Density (Air=1) Not determined.
Density (g/ml) 2.2 – 2.7
Solubility (Water) Negligible
Solubility (Other) Not known
Partition Coefficient (n-Octanol/water) Not available.
Auto Ignition Point (°C) Not available.
Decomposition Temperature (°C) Not available.
Kinematic Viscosity (cSt) @ 40°C Not available
Explosive properties Not explosive.
Oxidizing properties Not oxidizing.
Other information Not available.

 

 

Reactivity Stable under normal conditions.
Chemical stability Stable.
Possibility of hazardous reactions May react violently with: Strong oxidizing agents
Conditions to avoid Incompatible materials
Incompatible materials Oxidizers
Hazardous decomposition product(s) Combustion causes toxic fumes. Combustion products: Carbon monoxide, Carbon dioxide, Nitrogen oxides, Sulfur oxides

 

Exposure routes: Inhalation, Skin Contact, Eye Contact

Information on toxicological effects

 

 

Acute toxicity                                                        LD50 (rat): >5000 mg/kg bw LD50 (dermal): >2000 mg/kg bw

LC50 (inhalation, fume): >94.4 mg/m3

Irritation/Corrosivity                                            May cause irritation to skin, eyes and respiratory system.

Sensitization                                                        Not to be expected

Repeated dose toxicity                                       NOAEL(rat): 28 mg/m3 LOAEL (rat): 149 mg/m3

Carcinogenicity                                                   Not to be expected at typical road paving temperatures.

 

NTP IARC ACGIH OSHA
No. 2B* No. No.

Mutagenicity                                                         Not to be expected.

Reproductive toxicity                                          Not to be expected.

 

Other information  * IARC (2013, volume 103) identifies that “occupational exposures to straight-run bitumens and their emissions during road paving are possibly carcinogenic to humans (Group 2B).” However, classification as a carcinogen under OSHA 29 CFR 1910.1200 is not warranted given the absence of positive cancer findings in human epidemiological studies and in cancer studies with laboratory animals when exposed dermally or by inhalation to asphalt products or fume condensates that are typical of road paving applications. IARC (2013, volume 103) also identifies that “occupational exposures to oxidized bitumens and their emissions during roofing are probably carcinogenic to humans (Group 2A).” Roofing shingles, which are considered an article under OSHA 29 CFR 1910.1200, are sometimes recycled into road paving asphalt mix. Emissions from oxidized bitumen, e.g., from shingles, at road paving temperatures are not expected to be qualitatively different than emissions from straight-run bitumens, and therefore would not warrant a carcinogen classification under OSHA 29 CFR 1910.1200.

 

 

Ecotoxicity
Short term LL50 (48 hour): >1000 mg/l (Fish)

LL50 (48 hour): >1000 mg/L (Aquatic Invertebrates) EL50 (48 hour): >1000 mg/L (Aquatic Plants)

Long Term No data
Persistence and degradability The product is poorly biodegradable.
Bioaccumulative potential The product has low potential for bioaccumulation.
Mobility in soil The product has low mobility in soil.
Results of PBT and vPvB assessment Not classified as PBT or vPvB.
Other adverse effects None known.

 

 

Waste treatment methods Disposal should be in accordance with local, state or national legislation.Consult an accredited waste disposal contractor or the local authority for advice.
Additional Information None known.

 

 

Ground or Water Domestic Voyage (DOT): Not regulated when transported below 240°C (464 °F).

 

 

Safety, health and environmental regulations/legislation specific for the substance or mixture:
TSCA (Toxic Substance Control Act) – Inventory Status: All components listed or polymer exempt.

 

 

RCRA Hazardous Waste Number (40 CFR 261.33): None

US RCRA Hazard Class: Not applicable.

Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4):

 

Chemical Name CAS No. Typical %wt. RQ (Pounds)
None —– —– —–

SARA 311/312 – Hazard Categories: None

Fire          Sudden Release        Reactivity          Immediate (acute)          Chronic (delayed)

SARA 313 – Toxic Chemicals (40 CFR 372):

 

Chemical Name CAS No. Typical %wt.
None —– —–

SARA 302 – Extremely Hazardous Substances(40 CFR 355):

 

Chemical Name CAS No. Typical %wt. TPQ (pounds)
None —– —– —–

 

Additional Information

 

The following sections contain revisions or new statements: 1-16.

 

Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose. The manufacturer gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. The manufacturer accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information.

Freedom under Patents, Copyright and Designs cannot be assumed.